This Is AuburnAU Scholarly Repository
  1. AU Scholarly Repository Home
  2. College of Sciences and Mathematics
  3. Browsing College of Sciences and Mathematics by Subject

Browsing College of Sciences and Mathematics by Subject "Inorganic Chemistry"

Now showing items 1-3 of 3

An Fe(II) Complex Detects Hydrogen Peroxide with 1H and 19F Magnetic Resonance Imaging Responses 

Karbalaei, Sana; Franke, Alicja; Zahl, Achim; Pokkuluri, P. Raj; Beyers, Ronald J.; Ivanović-Burmazović, Ivana; Goldsmith, Christian R. (2026-01-15)  ETD File Embargoed
We report the fluorinated quinol-containing ligand, 1,8-bis(2,5-dihydroxy-4-fluorobenzyl)-1,4,8,11-tetraazacyclotetradecane (F2H4qp4), and its highly water- and air-stable Fe(II) complex. Upon oxidation by H2O2, the 19F ...

Nickel(II) Complexes with Covalently Attached Quinols Rely on Ligand-Derived Redox Couples to Catalyze Superoxide Dismutation 

Boothe, Robert; Oppelt, Julian; Franke, Alicja; Moore, Jamonica L.; Kellner, Ina; Awalah, Akudo L.; Bradford, Alisabeth; Obisesan, Segun V.; Schwartz, Dean D.; Ivanović-Burmazović, Ivana; Goldsmith, Christian R.; Squarcina, Andrea; Zahl, Achim; Senft, Laura; https://orcid.org/0000-0001-7293-1267 (2025-12-03)
Although nickel is found in the active sites of a class of superoxide dismutase (SOD), nickel complexes with non-peptidic ligands normally do not catalyze superoxide degradation, and none has displayed activity comparable ...

The Use of Intramolecular Quinol Redox Couples to Facilitate the Catalytic Transformation of O2 and O2-Derived Species 

Farnum, Byron H.; Goldsmith, Christian R. (2025-12-09)
The redox reactivity of transition metal centers can be augmented by nearby redox-active inorganic or organic moieties. In some cases, these functional groups can even allow a metal center to participate in reactions that ...